I am not sure there is a way with Druple but I have done it using mail forwarding. Hope this helps.
Thanks,
Steve
Steve Kessler
Denver DataMan
303-587-4428
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From: Rohan Smith [mailto:rohanasmith@gmail.com] Sent: Tuesday, November 11, 2008 2:51 PM To: support@drupal.org Subject: [support] User approval emails - to many admins
How do I allow the user approval emails to be sent to multiple admins? currently it is sent to user/1 's email (I think) or can it be set to multiple addresses?